(************** Content-type: application/mathematica ************** CreatedBy='Mathematica 5.1' Mathematica-Compatible Notebook This notebook can be used with any Mathematica-compatible application, such as Mathematica, MathReader or Publicon. The data for the notebook starts with the line containing stars above. To get the notebook into a Mathematica-compatible application, do one of the following: * Save the data starting with the line of stars above into a file with a name ending in .nb, then open the file inside the application; * Copy the data starting with the line of stars above to the clipboard, then use the Paste menu command inside the application. Data for notebooks contains only printable 7-bit ASCII and can be sent directly in email or through ftp in text mode. Newlines can be CR, LF or CRLF (Unix, Macintosh or MS-DOS style). NOTE: If you modify the data for this notebook not in a Mathematica- compatible application, you must delete the line below containing the word CacheID, otherwise Mathematica-compatible applications may try to use invalid cache data. For more information on notebooks and Mathematica-compatible applications, contact Wolfram Research: web: http://www.wolfram.com email: info@wolfram.com phone: +1-217-398-0700 (U.S.) Notebook reader applications are available free of charge from Wolfram Research. *******************************************************************) (*CacheID: 232*) (*NotebookFileLineBreakTest NotebookFileLineBreakTest*) (*NotebookOptionsPosition[ 32553, 909]*) (*NotebookOutlinePosition[ 33373, 937]*) (* CellTagsIndexPosition[ 33329, 933]*) (*WindowFrame->Normal*) Notebook[{ Cell[CellGroupData[{ Cell["Lamb shift", "Title", FontSize->16], Cell[CellGroupData[{ Cell["Introduction", "Section", FontSize->16], Cell["\<\ \tSuppose there is a one-electron state 0. An interation of electrons with \ the electromaelegnetic field mixes this state with a set of states N, in \ which the electron occupies some state n, and additionally there is a \ photon, which can be described by its momentum and polarization. As a \ result, in the second order of the perturbation theory there appears an \ energy shift of the level |0\[RightAngleBracket]. This shift, as well as \ physical reasons producing it, is called the Lab shift. \tA potential initiating this effect can be written in terms of the velocity \ of the electron and the vector potential \ \>", "Text", PageWidth->WindowWidth, CellMargins->{{Inherited, 0}, {Inherited, Inherited}}, CellSize->{458, Inherited}, TextAlignment->Left, TextJustification->0, FontSize->16], Cell[BoxData[ \(V = \(-e\)\ \(v\& \[Rule] \)\[CenterDot]\(A\& \[Rule] \)\)], \ "NumberedEquation", FontSize->16], Cell["\<\ Here the vector potential describes a photon with the given momentum and \ polarization \ \>", "Text", FontSize->16], Cell[BoxData[ \(\(\(\(A\& \[Rule] \) = \(\@\(\(4 \[Pi]\)\/\(2 \[Omega]\)\)\) \(\ \[Epsilon]\& \[Rule] \)\ Exp[\[ImaginaryI] \((\(k\& \[Rule] \)\[CenterDot]\(r\ \& \[Rule] \) - \[Omega]\ t)\)]\)\(,\)\)\)], "NumberedEquation", FontSize->16], Cell[BoxData[{ RowBox[{ RowBox[{\(k\& \[Rule] \), " ", ",", RowBox[{\(\[Epsilon]\& \[Rule] \), " ", StyleBox["are", FontFamily->"Times New Roman"], StyleBox[" ", FontFamily->"Times New Roman"], StyleBox["the", FontFamily->"Times New Roman"], StyleBox[" ", FontFamily->"Times New Roman"], StyleBox["momentum", FontFamily->"Times New Roman"], StyleBox[" ", FontFamily->"Times New Roman"], StyleBox["and", FontFamily->"Times New Roman"], StyleBox[" ", FontFamily->"Times New Roman"], StyleBox["polarization", FontFamily->"Times New Roman"]}], StyleBox[",", FontFamily->"Times New Roman"], StyleBox[" ", FontFamily->"Times New Roman"], StyleBox[\(\[Omega] = k\ is\ the\ photon\ frequency . \ \ The\ normalization\), FontFamily->"Times New Roman"]}], StyleBox[" ", FontFamily->"Times New Roman"]}], "\[IndentingNewLine]", RowBox[{ RowBox[{ StyleBox["factor", FontFamily->"Times New Roman"], StyleBox[" ", FontFamily->"Times New Roman"], StyleBox[\(\@\(2 \[Pi]/\[Omega]\)\), FontFamily->"Times New Roman"], StyleBox[" ", FontFamily->"Times New Roman"], StyleBox["is", FontFamily->"Times New Roman"], StyleBox[" ", FontFamily->"Times New Roman"], StyleBox["justified", FontFamily->"Times New Roman"], StyleBox[" ", FontFamily->"Times New Roman"], RowBox[{ StyleBox["below", FontFamily->"Times New Roman"], StyleBox[".", FontFamily->"Times New Roman"], "\[IndentingNewLine]", StyleBox[ RowBox[{"\t", StyleBox[" ", FontFamily->"Times New Roman"]}]], StyleBox["In", FontFamily->"Times New Roman"]}], StyleBox[" ", FontFamily->"Times New Roman"], StyleBox["the", FontFamily->"Times New Roman"], StyleBox[" ", FontFamily->"Times New Roman"], StyleBox["dipole", FontFamily->"Times New Roman"], StyleBox[" ", FontFamily->"Times New Roman"], StyleBox["approximation", FontFamily->"Times New Roman"]}], StyleBox[",", FontFamily->"Times New Roman"], StyleBox[\(which\ we\ will\ use\ below\), FontFamily->"Times New Roman"], StyleBox[",", FontFamily->"Times New Roman"], StyleBox[" ", FontFamily->"Times New Roman"], StyleBox[\(the\ vector - potential\ simplifies\), FontFamily->"Times New Roman"]}]}], "Text", FontSize->16], Cell[BoxData[ \(\(A\& \[Rule] \) \[TildeEqual] \@\(\(4 \[Pi]\)\/\(2 \ \[Omega]\)\)\ \ \(\[Epsilon]\& \[Rule] \)\ \ Exp[\(-\[ImaginaryI]\[Omega]\)\ \ t]\)], "NumberedEquation", FontSize->16], Cell[BoxData[ StyleBox[\(The\ matrix\ element, \ which\ mixes\ the\ states\ 0\ and\ N\ reads\), FontFamily->"Times New Roman"]], "Text", FontSize->16], Cell[BoxData[ \(V\_\(N, 0\) = \(-e\)\ \@\(\(4 \[Pi]\)\/\(2 \[Omega]\)\)\ \(\(\(v\& \ \[Rule] \)\_\(n, 0\)\ \[CenterDot]\ \ \(\[Epsilon]\& \[Rule] \)\)\(\ \)\)\)], \ "NumberedEquation", FontSize->16], Cell["For the energy shift one finds ", "Text", FontSize->16], Cell[BoxData[{ \(\[Delta]E\_0 = \[Sum]\+N\(\(|\)\(V\_\(N, 0\)\)\( | \^2\)\)\/\(E\_0 - \ E\_N\)\), "\n", \(\(\(=\)\(4 \[Pi]\ \(e\^2\) \(\[Sum]\+\(k, \[Epsilon]\)\(\[Sum]\+n\( 1\/\(2 \[Omega]\)\) \(\(|\)\(\(v\& \[Rule] \)\_\(n, 0\)\ \ \[CenterDot]\ \ \(\[Epsilon]\& \[Rule] \)\)\(\ \)\( | \^2\)\)\/\(E\_0 - E\_n \ - \[Omega]\)\)\) = \[IndentingNewLine]4 \[Pi]\ \(e\^2\) \(\[Sum]\+\(\ \[Epsilon] = 1, 2\)\[Integral]\(\[DifferentialD]\^3 k\/\((2 \[Pi])\)\^3\) \(\[Sum]\+n\( 1\/\(2 \[Omega]\)\) \(\(|\)\(\(v\& \[Rule] \)\_\(n, \ 0\)\ \[CenterDot]\ \ \(\[Epsilon]\& \[Rule] \)\)\(\ \)\( | \^2\)\)\/\(E\_0 - \ E\_n - \[Omega]\)\)\)\)\)\)}], "NumberedEquation", FontSize->16], Cell["\<\ Here it is taken into account that the summation over the photon intemediate \ states results in the integral over the photon momentum and summation over \ its polarixation. \ \>", "Text", FontSize->16] }, Open ]], Cell[CellGroupData[{ Cell["Normalization of the vector potential", "Section", FontSize->16], Cell[CellGroupData[{ Cell["Preliminary remarks", "Subsection", FontSize->16], Cell["\<\ Suppose one needs to fulfill summation over a set of a continuum states of \ some particle. One can take some large volume, call it V, and assume that it \ is greater than the volume in which physical events considered take place. \ Then instead of summation over the continuum states one fulfilles summation \ over quasi-continuum set of states, for which periodical boundary conditions \ in the volume V are valid. After that one rewrites the summation as the \ integral using the following formulae \ \>", "Text", FontSize->16], Cell[BoxData[ \(\[Sum]\+n\( \[Psi]\_\(\(p\& \[Rule] \)\_n\)\) \((\(r\& \[Rule] \))\) \(\ \[Psi]\_\(\(p\& \[Rule] \)\_n\)\%*\) \((\(r\& \[Rule] \)')\)\ \( \[Rule] \ \+\(V \[Rule] \[Infinity]\)\)\ V \(\[Integral]\(\[DifferentialD]\^3 p\/\((2 \[Pi])\)\^3\) \(\[Psi]\_\(p\& \[Rule] \ \)\%\((V)\)\) \((\(r\& \[Rule] \))\) \(\[Psi]\_\(p\& \[Rule] \)\%\(\((V)\)\(*\ \)\)\) \((\(r\& \[Rule] \)')\)\)\)], "NumberedEquation", FontSize->16], Cell["\<\ Here the superscript (V) indicates that the wave functions on the right-hand \ side are normalized in the volume V. Instead of this normalization it is \ convenient to introduce normalization for unit volume, in which the following \ obvious identity holds \ \>", "Text", FontSize->16], Cell[BoxData[ \(\(\[Psi]\_\(p\& \[Rule] \)\%\((V)\)\) \((\(r\& \[Rule] \))\) = \(1\/\@V\ \) \(\[Psi]\_\(p\& \[Rule] \)\%\((V = 1)\)\) \((\(r\& \[Rule] \))\)\)], "NumberedEquation", FontSize->16], Cell["Then the necessary summation reads", "Text", FontSize->16], Cell[BoxData[ \(\[Sum]\+n\( \[Psi]\_\(\(p\& \[Rule] \)\_n\)\) \((\(r\& \[Rule] \))\) \(\ \[Psi]\_\(\(p\& \[Rule] \)\_n\)\%*\) \((\(r\& \[Rule] \)')\)\ = \ \ \[Integral]\(\[DifferentialD]\^3 p\/\((2 \[Pi])\)\^3\) \(\[Psi]\_\(p\& \[Rule] \)\) \((\(r\& \ \[Rule] \))\) \(\[Psi]\_\(p\& \[Rule] \)\%*\) \((\(r\& \[Rule] \)')\)\)], \ "NumberedEquation", FontSize->16], Cell[TextData[{ "where the superscript (V=1) is suppressed.\n\tThus, to fulfil summation \ over the continuum set of states one can integrate over the momentum ", Cell[BoxData[ \(TraditionalForm\`\[DifferentialD]\^3 p/\((2 \[Pi])\)\^3\)]], ", normalizing wave functions as \"one particle per unit volume\"." }], "Text", FontSize->16] }, Open ]], Cell[CellGroupData[{ Cell["Photons", "Subsection", FontSize->16], Cell[BoxData[ \(\[LeftAngleBracket]0 | \ \(\(A\& \[Rule] \)\_\(k\& \[Rule] \)\^*\) \ \(A\& \[Rule] \)\_\(k\& \[Rule] \) | 0\[RightAngleBracket] = \(\[Sum]\+m\[LeftAngleBracket]0 | \ \(\(A\& \ \[Rule] \)\_\(k\& \[Rule] \)\^*\) | m\[RightAngleBracket] \[LeftAngleBracket]m | \(A\& \[Rule] \)\ \_\(k\& \[Rule] \) | 0\[RightAngleBracket] = \(\[LeftAngleBracket]0 | \ \(\(A\& \ \[Rule] \)\_\(k\& \[Rule] \)\^*\) | 1\[RightAngleBracket] \[LeftAngleBracket]1 | \(A\& \[Rule] \)\ \_\(k\& \[Rule] \) | 0\[RightAngleBracket] = \(\(|\)\(\[LeftAngleBracket]1 | \(A\& \ \[Rule] \)\_\(k\& \[Rule] \) | 0\[RightAngleBracket]\)\( | \^2\)\)\)\)\)], "NumberedEquation",\ FontSize->16], Cell["\<\ A photon represents a harmonic oscillator. Therefore the avaraged kinetic and \ potential energies equal half of the total energy. In the vacuum this total \ energy is half of the frequency. In this case\ \>", "Text", FontSize->16], Cell[BoxData[ \(\(T\&-\) = \(\(U\&-\) = \(\(1\/2\) E = \(1\/4\) \[Omega]\)\)\)], "NumberedEquation", FontSize->16], Cell["\<\ The kinetic energy of the oscillator can be expressed using the energy of the \ electromagnetic field in a unit volume, which reads\ \>", "Text", FontSize->16], Cell[BoxData[ \(d\[CurlyEpsilon]\/dV = \(\(|\)\(\(E\& \[Rule] \)\_\(k\& \[Rule] \)\)\( \ | \^2\)\(+\(\(|\)\(\(H\& \[Rule] \)\_\(k\& \[Rule] \)\)\( | \^2\)\)\)\)\/\(8 \ \[Pi]\)\)], "NumberedEquation", FontSize->16], Cell["\<\ Here the energy is calculated \"per unit volume\", precisely as is necessary \ for the purposes of integration over the continuum states of the photon, see \ above. Since\ \>", "Text", FontSize->16], Cell[BoxData[ \(\(E\& \[Rule] \)\_\(k\& \[Rule] \) = \(-\(\[PartialD]\/\[PartialD]t\)\) \ \(A\& \[Rule] \)\_\(k\& \[Rule] \)\)], "NumberedEquation", FontSize->16], Cell["the first term in the energy represents the kinetic energy ", "Text", FontSize->16], Cell[BoxData[{ \(T = \(\(\(|\)\(\(E\& \[Rule] \)\_\(k\& \[Rule] \)\)\( | \^2\)\) = \(\ \[Omega]\^2\) \(\(A\& \[Rule] \)\_\(k\& \[Rule] \)\^*\) \(A\& \[Rule] \)\_\(k\ \& \[Rule] \)\)\), "\[IndentingNewLine]", \(\(T\&-\) = \(\[LeftAngleBracket]0 | T | 0\[RightAngleBracket] = \(\[Omega]\^2\/\(8 \[Pi]\)\) \ \[LeftAngleBracket]0 | \(\(A\& \[Rule] \)\_\(k\& \[Rule] \)\^*\) \(A\& \ \[Rule] \)\_\(k\& \[Rule] \) | 0\[RightAngleBracket]\)\)}], "NumberedEquation",\ FontSize->16], Cell["Combining this with the previous disscussion one finds", "Text", FontSize->16], Cell[BoxData[ \(\(T\&-\)\ = \ \(\[Omega]\^2\/\(8 \[Pi]\) | \[LeftAngleBracket]1 | \(A\ \& \[Rule] \)\_\(k\& \[Rule] \) | 0\[RightAngleBracket]\( | \^2\) = \(1\/4\) \[Omega]\)\)], \ "NumberedEquation", FontSize->16], Cell["\<\ Thus considering creation (or annialation) of one photn one should have \ \>", "Text", FontSize->16], Cell[BoxData[ \(\[LeftAngleBracket]1 | \(A\& \[Rule] \)\_\(k\& \[Rule] \) | 0\[RightAngleBracket] = \@\(\(4 \[Pi]\)\/\(2 \[Omega]\)\)\)], \ "NumberedEquation", FontSize->16] }, Open ]] }, Open ]], Cell[CellGroupData[{ Cell["Energy sfift", "Section", FontSize->16], Cell[BoxData[ \(\[Delta]E\_0 = \(4 \[Pi]\ \(e\^2\) \(\[Sum]\+\(\[Epsilon] = 1, 2\)\ \[Integral]\(\[DifferentialD]\^3 k\/\((2 \[Pi])\)\^3\) \(\[Sum]\+n\( 1\/\(2 \[Omega]\)\) \(\(|\)\(\(v\& \[Rule] \)\_\(n, \ 0\)\ \[CenterDot]\ \ \(\[Epsilon]\& \[Rule] \)\)\(\ \)\( | \^2\)\)\/\(E\_0 - \ E\_n - \[Omega]\)\)\) = 4 \[Pi]\ \(e\^2\) \(\[Sum]\+n\[Integral]\+0\%\[Infinity]\(\(\( \ \[Omega]\^2\) \[DifferentialD]\[Omega]\)\/\((2 \[Pi])\)\^3\) \(1\/\(2 \ \[Omega]\)\) \(1\/\(E\_0 - E\_n - \[Omega]\)\) \(\[Integral]\[Sum]\+\(\[Epsilon] \ = 1, 2\)\)\) | \(v\& \[Rule] \)\_\(n, 0\)\ \[CenterDot]\ \ \(\[Epsilon]\& \ \[Rule] \)\ \( | \^2\)\[DifferentialD]\[CapitalOmega]\)\)], "NumberedEquation",\ FontSize->16], Cell["\<\ Here \[DifferentialD]\[CapitalOmega] represents integration over the \ spherical angle of the photon momentum\ \>", "Text", FontSize->16], Cell[BoxData[ \(\[Integral]\[Sum]\+\(i = 1, 2\) | \(v\& \[Rule] \)\_\(n, 0\)\ \ \[CenterDot]\ \ \(\[Epsilon]\& \[Rule] \)\_i\ \( | \^2\)\[DifferentialD]\ \[CapitalOmega] = \(\[Integral]\((\(|\)\(\(v\& \[Rule] \)\_\(n, 0\)\)\( | \^2\)\(-\(\(|\)\(\(v\& \[Rule] \)\_\(n, 0\)\ \[CenterDot]\(n\& \[Rule] \)\)\( | \^2\)\)\))\)\ \[DifferentialD]\ \[CapitalOmega] = \(\(\(|\)\(\(v\& \[Rule] \)\_\(n, 0\)\)\( | \^2\)\(\[Integral]\+\(4 \[Pi]\)\((1 - Cos[\[Theta]]\^2)\) \[DifferentialD]\[CapitalOmega]\)\) = \ \[IndentingNewLine]\(\(\(|\)\(\(v\& \[Rule] \)\_\(n, 0\)\)\( | \^2\)\(2 \[Pi] \(\[Integral]\+0\%\[Pi]\((1 - Cos[\[Theta]]\^2)\) Sin[\[Theta]] \[DifferentialD]\[Theta]\)\)\) = \(2\/3\) 4 \[Pi] | \(v\& \[Rule] \)\_\(n, 0\)\( | \^2\)\)\)\), \ \[IndentingNewLine]\(n\& \[Rule] \) = \(\(\(k\& \[Rule] \)\/k\)\(.\)\)\)], \ "NumberedEquation", FontSize->16], Cell["\<\ Thus, summation over the polarization and integration over the angles for a \ dipole transition gives a factor 2/3\ \>", "Text", FontSize->16], Cell[BoxData[{ \(\[Delta]E\_0 = \(\(4 \[Pi]\ e\^2\)\/\((2 \[Pi])\)\^3\) \(1\/2\) \ \(2\/3\) 4 \[Pi] \(\(\ \ \)\(\[Sum]\)\)\+n | \(v\& \[Rule] \)\_\(n, 0\)\( | \ \^2\)\[Integral]\+0\%\[Infinity]\[DifferentialD]\[Omega]\ \(\[Omega]\^2\) \(1\ \/\[Omega]\) 1\/\(E\_0 - E\_n - \[Omega]\)\), "\[IndentingNewLine]", \(\(\(=\)\(\(2\/\(3 \[Pi]\)\) \(e\^2\) \(\(\ \)\(\[Sum]\)\)\+n | \(v\& \ \[Rule] \)\_\(n, 0\)\( | \^2\)\[Integral]\+0\%\[Infinity]\[DifferentialD]\ \[Omega]\ \[Omega]\/\(E\_0 - E\_n - \[Omega]\)\)\)\)}], "NumberedEquation", FontSize->16], Cell[CellGroupData[{ Cell["Renormalization", "Subsection", FontSize->16], Cell["Repeating the argument for the vacuum one can write", "Text", FontSize->16], Cell[BoxData[ \(\((\[Delta]E\_0)\)\_vac = \ \(\(2 e\^2\)\/\(3\ \[Pi]\)\) \(\(\ \)\(\[Sum]\)\)\+n | \(v\& \ \[Rule] \)\_\(n, 0\)\( | \^2\)\[Integral]\+0\%\[Infinity]\[DifferentialD]\ \[Omega]\ \[Omega]\/\(-\[Omega]\)\)], "NumberedEquation", FontSize->16], Cell["\<\ since in the vacuum the operator of velocity does not have nondiagonal matrix \ elements. For the energy difference one finds\ \>", "Text", FontSize->16], Cell[BoxData[ \(\((\[Delta]E\_0)\)\_ren = \(\[Delta]E\_0 - \((\[Delta]E\_0)\)\_vac = \ \[IndentingNewLine]\(\(=\)\(\(\(2 e\^2\)\/\(3 \[Pi]\)\) \(\(\ \)\(\[Sum]\)\)\+n | \(v\& \ \[Rule] \)\_\(n, 0\)\( | \^2\)\[Integral]\+0\%\[Infinity]\[DifferentialD]\ \[Omega]\ \((\[Omega]\/\(E\_0 - E\_n - \[Omega]\) + 1)\) = \(\(2 e\^2\)\/\(3 \[Pi]\)\) \(\(\ \)\(\[Sum]\)\)\+n | \(v\& \ \[Rule] \)\_\(n, 0\)\( | \^2\)\[Integral]\+0\%\[Infinity]\[DifferentialD]\ \[Omega]\ \(E\_0 - E\_n\)\/\(E\_0 - E\_n - \[Omega]\)\)\)\)\)], \ "NumberedEquation", FontSize->16], Cell["\<\ In the following discussion the subscript ren (for renormalized) is \ suppressed. \tThe physical picture considered can be only correct in the nonrelativistic \ approximation. Therefore the integration over \[Omega] should run only up to \ m (not to infinity, where different formulas need to be worked out).\ \>", "Text", FontSize->16], Cell[BoxData[ \(\[Delta]E\_0 \[Implies] \(\(2 e\^2\)\/\(3 \[Pi]\)\) \(\(\ \)\(\[Sum]\)\)\+n | \(v\& \ \[Rule] \)\_\(n, 0\)\( | \^2\)\[Integral]\+0\%m\[DifferentialD]\[Omega]\ \ \(E\_0 - E\_n\)\/\(E\_0 - E\_n - \[Omega]\) = \(-\(\(2 e\^2\)\/\(3 \[Pi]\)\)\) \(\(\(\ \)\(\[Sum]\)\)\+n\) \ \((E\_0 - E\_n)\) | \(v\& \[Rule] \)\_\(n, 0\)\( | \^2\)Log[ m\/\(E\_0 - E\_n\)]\)], "NumberedEquation", FontSize->16], Cell[BoxData[ \(\(v\& \[Rule] \)\_\(n, 0\) = \(\(1\/m\) \(p\& \[Rule] \)\_\(n, 0\) \ \[Congruent] \(1\/m\) \[LeftAngleBracket]n | \(p\& \[Rule] \) | 0\[RightAngleBracket] = \(\(\[ImaginaryI]\/m\) \ \[LeftAngleBracket]n | \[ImaginaryI][H \( r\& \[Rule] \)] | 0\[RightAngleBracket] = \[ImaginaryI] \(\( E\_0 - E\_n\)\/m\) \[LeftAngleBracket]n | \(r\& \[Rule] \) | 0\[RightAngleBracket] \[Congruent] \(\(E\_0 - E\_n\)\/m\) \(r\& \[Rule] \)\_\(n, 0\)\)\)\)], \ "NumberedEquation", FontSize->16], Cell[BoxData[ \(\[Delta]E\_0 = \(\(-\(\(2 e\^2\)\/\(3 \[Pi]\)\)\) \(\(\(\ \)\(\[Sum]\)\)\+n\) \ \((E\_0 - E\_n)\)\^3 | \(r\& \[Rule] \)\_\(n, 0\)\( | \^2\)Log[ m\/\(E\_0 - E\_n\)] = \(\(2 e\^2\)\/\(3 \[Pi]\)\) \(\(\(\ \)\(\[Sum]\)\)\+n\) \((E\_n \ - E\_0)\)\^3 | \(r\& \[Rule] \)\_\(n, 0\)\( | \^2\)Log[ m\/\(E\_0 - E\_n\)]\)\)], "NumberedEquation", FontSize->16], Cell["\<\ This expression has a real and imaginary parts. The latter will be discussed \ when radiative widths are considered. For the real part, which represents a \ proper energy, one finds\ \>", "Text", FontSize->16], Cell[BoxData[ \(Re[\[Delta]E\_0] = \(\(2 e\^2\)\/\(3 \[Pi]\)\) \(\(\(\ \)\(\[Sum]\)\)\+n\) \((E\_n - \ E\_0)\)\^3 | \(r\& \[Rule] \)\_\(n, 0\)\( | \^2\)Log[ m\/\(\(|\)\(E\_n - E\_0\)\(|\)\)]\)], "NumberedEquation", FontSize->16], Cell["In absolute units", "Text", FontSize->16], Cell[BoxData[ \(Re[\[Delta]E\_0] = \(2\/\(3 \[Pi]\ c\^3\)\) \(\(\(\ \ \)\(\[Sum]\)\)\+n\) \[Omega]\_\(n, 0\)\%3 | \(d\& \[Rule] \)\_\(n, 0\)\( | \ \^2\)Log[\(m\ c\^2\)\/\(\(|\)\(E\_n - E\_0\)\(|\)\)]\)], "NumberedEquation", FontSize->16], Cell["where", "Text", FontSize->16], Cell[BoxData[ \(\[Omega]\_\(n, 0\) = \(E\_n - E\_0\)\/\:f7d8\)], "NumberedEquation", FontSize->16], Cell[CellGroupData[{ Cell["Large Log approximation ", "Subsubsection", FontSize->16], Cell["For atoms", "Text", FontSize->16], Cell[BoxData[ \(E\_n - E\_0 \[Tilde] \(Z\^2\) Ry\)], "NumberedEquation", FontSize->16], Cell[BoxData[ \(Log[\(m\ c\^2\)\/\(\(|\)\(E\_n - E\_0\)\(|\)\)] \[TildeEqual] Log[1\/\((Z\[Alpha])\)\^2]\ \[GreaterGreater] \ 1\)], "NumberedEquation", FontSize->16], Cell["assuming that (Z\[Alpha])\[LessLess]1.", "Text", FontSize->16], Cell[BoxData[ \(Re[\[Delta]E\_0] \[TildeEqual] \(\(2 e\^2\)\/\(\(3\) \(\[Pi]\)\(\ \)\)\) Log[1\/\((Z\[Alpha])\)\^2] \(\(\(\ \)\(\[Sum]\)\)\+n\) \((E\_n - \ E\_0)\)\^3 | \(r\& \[Rule] \)\_\(n, 0\)\( | \^2\)\)], "NumberedEquation", FontSize->16] }, Open ]], Cell[CellGroupData[{ Cell[BoxData[ \(Effective\ potential\ \[Tilde] \ \((e\^2/ m)\) \[CapitalDelta]U\)], "Subsubsection", FontSize->16], Cell[BoxData[{ \(Re[\[Delta]E\_0] = \(\(\(2 e\^2\)\/\(\(3\) \(\[Pi]\)\(\ \)\)\) Log[1\/\((Z\[Alpha])\)\^2] \(\(\(\ \)\(\[Sum]\)\)\+n\) \((E\_n - \ E\_0)\)\^3 | \(r\& \[Rule] \)\_\(n, 0\)\( | \^2\) = \(\(\(2 e\^2\)\/\(\(3\) \(\[Pi]\)\(\ \)\)\) Log[1\/\((Z\[Alpha])\)\^2] \(\(\(\ \)\(\[Sum]\)\)\+n\) \((E\_n - E\_0)\) \[LeftAngleBracket]0 | \(v\& \[Rule] \) | n\[RightAngleBracket] \[LeftAngleBracket]n | \(v\& \[Rule] \) \ | 0\[RightAngleBracket] = \[IndentingNewLine]\(\(2 e\^2\)\/\(3 \[Pi]\ m\^2\)\) Log[1\/\((Z\[Alpha])\)\^2] \(\(\(\ \)\(\[Sum]\)\)\+n\) \((E\_n - E\_0)\) \[LeftAngleBracket]0 | \(p\& \[Rule] \) | n\[RightAngleBracket] \[LeftAngleBracket]n | \(p\& \[Rule] \) \ | 0\[RightAngleBracket]\)\)\), "\[IndentingNewLine]", \(\(\(2 e\^2\)\/\(\(3\) \(\[Pi]\)\(\ \)\)\) Log[1\/\((Z\[Alpha])\)\^2]\[Cross]\(1\/\(\(2\)\(\[IndentingNewLine]\) \)\) \(\[Sum]\+n\((\[LeftAngleBracket]0 | \(p\& \[Rule] \) | n\[RightAngleBracket] \[LeftAngleBracket]n | \([H, \ \ \(p\& \[Rule] \)]\) | 0\[RightAngleBracket] - \[LeftAngleBracket]0 | \([H, \ \ \(p\& \[Rule] \)]\) | n\[RightAngleBracket] \[LeftAngleBracket]n | \(p\& \ \[Rule] \) | 0\[RightAngleBracket])\)\) = \(Re[\[Delta]E\_0] = \ \(e\^2\/\(\(3\) \(\[Pi]\)\(\ \)\(m\^2\)\(\ \)\)\) Log[1\/\((Z\[Alpha])\)\^2] S\_0\)\)}], "NumberedEquation", FontSize->16], Cell[BoxData[ \(S\_0 = \[Sum]\+n\((\[LeftAngleBracket]0 | \(p\& \[Rule] \) | n\[RightAngleBracket] \[LeftAngleBracket]n | \([H, \ \(p\& \ \[Rule] \)]\) | 0\[RightAngleBracket] - \[LeftAngleBracket]0 | \([H, \ \ \(p\& \[Rule] \)]\) | n\[RightAngleBracket] \[LeftAngleBracket]n | \(p\& \[Rule] \ \) | 0\[RightAngleBracket])\)\)], "NumberedEquation", FontSize->16], Cell[BoxData[ \(\(\(\[IndentingNewLine]\)\(\[Sum]\+n\(\(|\)\(n\ > < n\)\(|\)\) = 1\[IndentingNewLine] S\_0 = \(\[LeftAngleBracket]0 | \(p\& \[Rule] \)[ H, \ \(p\& \[Rule] \)] - \([H, \ \(p\& \[Rule] \)]\) \(p\& \ \[Rule] \) | 0\[RightAngleBracket] = \[LeftAngleBracket]0 | \([\(p\& \[Rule] \ \), \([H, \ \(p\& \[Rule] \)]\)]\) | 0\[RightAngleBracket]\)\)\)\)], "NumberedEquation", FontSize->16], Cell[BoxData[ \(\(\(\[IndentingNewLine]\)\(H = \(p\& \[Rule] \)\^2\/\(2 m\) + U \((r)\)\)\)\)], "NumberedEquation", FontSize->16], Cell[BoxData[{ \(\([H, \ \(p\& \[Rule] \)]\) = \[ImaginaryI]\ \(\[Del]\& \[Rule] \)U\), \ "\[IndentingNewLine]", \(\([\(p\& \[Rule] \), \([H, \ \(p\& \[Rule] \)]\)]\) = \ \(\[ImaginaryI][\(p\& \[Rule] \), \(\[Del]\& \[Rule] \)U] = \(\(\[Del]\& \ \[Rule] \)\(\(\[CenterDot]\)\(\(\[Del]\& \[Rule] \)U\)\) = \[CapitalDelta]U\)\ \)\)}], "NumberedEquation", FontSize->16], Cell[BoxData[ \(S\_0 = \[CapitalDelta]U\)], "NumberedEquation", FontSize->16], Cell[BoxData[ \(Re[\[Delta]E\_0] = \(e\^2\/\(\(3\) \(\[Pi]\)\(\ \)\(m\^2\)\(\ \)\)\) Log[1\/\((Z\[Alpha])\)\^2] \[LeftAngleBracket]0 | \[CapitalDelta]U | 0\[RightAngleBracket]\)], "NumberedEquation", FontSize->16], Cell[BoxData[ \(\(\[Delta]U\_eff\) \((r)\) = \(1\/\(\(3\) \(\[Pi]\)\(\ \ \)\)\) Log[1\/\((Z\[Alpha])\)\^2] \(e\^2\/\(\(m\^2\)\(\ \)\)\) \ \[CapitalDelta]U \((r)\)\)], "NumberedEquation", FontSize->16], Cell[BoxData[ \(U = \(-\(Ze\^2\/r\)\)\)], "NumberedEquation", FontSize->16], Cell[BoxData[ \(\[CapitalDelta] 1\/r = \(-4\) \[Pi]\ \[Delta] \((\(r\& \[Rule] \))\)\)], \ "NumberedEquation", FontSize->16], Cell[BoxData[ \(\[CapitalDelta]U = 4 \[Pi]\ Z\ e\^2\ \[Delta] \((\(r\& \[Rule] \))\)\)], \ "NumberedEquation", FontSize->16], Cell[BoxData[ \(\[Delta]E\_0 = \(\(4 Z\ e\^4\)\/\(\(3\)\(\ \)\(m\^2\)\(\ \)\)\) Log[1\/\((Z\[Alpha])\)\^2] \(\[CurlyPhi]\_0\%2\) \((0)\)\)], \ "NumberedEquation", FontSize->16], Cell["\<\ In the log approximation only the s-states exibit the Lamb shift. Other \ states are also influenced by the Lamb correction, but is does not have the \ large log factor. \ \>", "Text", FontSize->16], Cell[BoxData[ \(\(\[CurlyPhi]\_\(ns\_\(1/ 2\)\)\) \((0)\) = \(\@\(Z\^3\/\(\[Pi]\ \(a\_0\%3\) n\^3\)\) \ = \@\(\(\(Z\^3\) \[Alpha]\^3\ m\^3\)\/\(\(\[Pi]\)\(\ \)\(n\^3\)\(\ \ \)\)\)\)\)], "NumberedEquation", FontSize->16], Cell[BoxData[{ \(\[Delta]E\_\(ns\_\(1/2\)\) \[TildeEqual] \(\(4 Z\ e\^4\)\/\(\(3\)\(\ \)\(m\^2\) \(n\^3\)\(\ \)\)\) \ \(\(\(Z\^3\) \[Alpha]\^3\ m\^3\)\/\(\(\[Pi]\)\(\ \)\)\) Log[1\/\((Z\[Alpha])\)\^2] = \(\(4 Z\^4\ \[Alpha]\^5\ m\)\/\(3\ \[Pi]\ n\^3\)\) Log[1\/\((Z\[Alpha])\)\^2]\), "\[IndentingNewLine]", \(\[Delta]E\_\(np\_\(1/2\)\) \[TildeEqual] \[Delta]E\_\(np\_\(3/2\)\) \ \[TildeEqual] 0\), "\[IndentingNewLine]", \(\)}], "NumberedEquation", FontSize->16], Cell["Accurate relativistic calculations give", "Text", FontSize->16], Cell[BoxData[{\(\[Delta]E\_\(ns\_\(1/2\)\) = \(\(4 Z\^4\ \[Alpha]\^5\ m\ c\^2\)\/\(3\ \[Pi]\ n\^3\)\) \((Log[ 1\/\((Z\[Alpha])\)\^2] + 19\/30 + L\_n)\)\), "\[IndentingNewLine]", TagBox[GridBox[{ { "n", \(\(\ \ \)\(1\)\), \(\(\ \ \)\(2\)\), \(\(\ \ \)\(3\)\), \ \(\(\ \ \)\(\[Infinity]\)\)}, {\(L\_n\), \(-2.984`\), \(-2.812`\), \(-2.768`\), \(-2.721`\)} }, RowSpacings->1, ColumnSpacings->3, RowAlignments->Baseline, ColumnAlignments->{Left}], Function[ BoxForm`e$, TableForm[ BoxForm`e$]]]}], "NumberedEquation", FontSize->16], Cell[BoxData[ \(\(\(\ \ \ \)\(E\_0 \[Tilde] \(Z\^2\) \(\[Alpha]\^2\) m\[IndentingNewLine]\[IndentingNewLine] \[Delta]E\_0\/E\_0 \[Tilde] \(Z\^2\) \(\[Alpha]\^3\) Log[1\/\((Z\[Alpha])\)\^2]\)\)\)], "NumberedEquation", FontSize->16], Cell[BoxData[{ \(In\ Hydrogen\), "\[IndentingNewLine]", \(\[Delta]E\_\(2 s\_\(1/2\)\) - E\_\(2 p\_\(1/2\)\) \[TildeEqual] 1050\ MHz\)}], "NumberedEquation", FontSize->16] }, Open ]] }, Open ]] }, Open ]], Cell[CellGroupData[{ Cell["Radiative decay of excited levels", "Section", FontSize->16], Cell["\<\ For a quasistationary state 0 the energy has its real and imaginary parts\ \>", "Text", FontSize->16], Cell[BoxData[ \(E\_0 = Re[E\_0] - \[ImaginaryI]\ \[CapitalGamma]\/2\)], "NumberedEquation", FontSize->16], Cell["\[CapitalGamma] is called the width", "Text", FontSize->16], Cell[BoxData[ \(\[Psi] \[Tilde] \ Exp[\(-\[ImaginaryI]\)\ E\ t] = Exp[\(-\[ImaginaryI]\)\ Re[E\_0]\ t - \(\[CapitalGamma]\/2\) t], \[IndentingNewLine]\(\(Probability\)\(\ \)\(\[Tilde]\)\) | \ \[Psi]\( | \^2\)\(\(\[Tilde]\)\(Exp[\(-\[ImaginaryI]\)\ \[CapitalGamma]\ t]\)\ \)\)], "NumberedEquation", FontSize->16], Cell[TextData[{ "This means that probability of the decay ", StyleBox["W ", FontSlant->"Italic"], "(of the excited state) per second equals the width" }], "Text", FontSize->16], Cell[BoxData[ \(W = \[CapitalGamma] \[Congruent] \[CapitalGamma]\/\:f7d8\)], \ "NumberedEquation", FontSize->16], Cell["From the expression for the Lamb shift (see the Lamb shift) ", "Text", FontSize->16], Cell[BoxData[ \(\[Delta]E\_0 = \(\(2 e\^2\)\/\(3 \[Pi]\)\) \(\(\(\ \)\(\[Sum]\)\)\+n\) \((E\_n - \ E\_0)\)\^3 | \(r\& \[Rule] \)\_\(n, 0\)\( | \^2\)Log[ m\/\(E\_0 - E\_n\)]\)], "NumberedEquation", FontSize->16], Cell["one finds", "Text", FontSize->16], Cell[BoxData[ \(Im[\[Delta]E\_0] = \(\(\(2 e\^2\)\/\(3 \[Pi]\)\) \(\(\(\ \)\(\[Sum]\)\)\+n\) \((E\_n \ - E\_0)\)\^3 | \(r\& \[Rule] \)\_\(n, 0\)\( | \^2\)Im[ Log[m\/\(E\_0 - E\_n\)]] = \[IndentingNewLine]\(\(-\(\(2 e\^2\)\/3\)\) \(\(\(\ \)\(\[Sum]\)\)\+\(E\_n < E\_0\)\) \((E\_0 - E\_n)\)\^3 | \(r\& \[Rule] \)\_\(n, \ 0\)\( | \^2\) = \(-\(2\/3\)\) \(\(\(\ \)\(\[Sum]\)\)\+\(E\_n < E\_0\)\) \[Omega]\_\(0 n\)\%3 | \(d\& \[Rule] \)\_\(n, 0\ \)\( | \^2\)\)\)\)], "NumberedEquation", FontSize->16], Cell["This means that the radiative width of the state 0 equals", "Text", FontSize->16], Cell[BoxData[ \(\[CapitalGamma]\/2 = \(2\/3\) \(\(\(\ \)\(\[Sum]\)\)\+\(E\_n < E\_0\)\) \[Omega]\_\(0 n\)\%3 | \(d\& \[Rule] \)\_\(n, 0\)\( \ | \^2\)\)], "NumberedEquation", FontSize->16], Cell["\<\ Correspondingly, the probability of the radiative decay of the state 0 is\ \>", "Text", FontSize->16], Cell[BoxData[ \(W = \(\(\(\(\ \)\(\[Sum]\)\)\+\(E\_n < E\_0\)\) W\_\(0 \[Rule] n\) = \(4\/3\) \(\(\(\ \)\(\[Sum]\)\)\+\(E\_n < E\_0\)\) \[Omega]\_\(0 n\)\%3 | \(d\& \[Rule] \)\_\(n, 0\)\ \( | \^2\)\)\)], "NumberedEquation", FontSize->16], Cell["Here ", "Text", FontSize->16], Cell[BoxData[ \(W\_\(0 \[Rule] n\) = \(4\/3\) \[Omega]\_\(0 n\)\%3 | \(d\& \[Rule] \ \)\_\(n, 0\)\( | \^2\)\(\(\[Congruent]\)\(\(4 \[Omega]\_\(0 n\)\%3\)\/\(3 \ \:f7d8\ c\^3\)\)\) | \(d\& \[Rule] \)\_\(n, 0\)\( | \^2\)\)], \ "NumberedEquation", FontSize->16], Cell["\<\ is the probability of the decay into some given state n, while W is the total \ probability of the radiative decay, \ \>", "Text", FontSize->16], Cell[BoxData[ \(\(d\& \[Rule] \)\_\(n, 0\) = \(e\ \(r\& \[Rule] \)\_\(n, 0\) = e \(\[Integral]\(\[Psi]\_n\%*\) \((\(r\& \[Rule] \))\) \(r\& \[Rule] \ \)\ \(\[Psi]\_0\) \((\(r\& \[Rule] \))\)\ \[DifferentialD]\^3 r\) \[Congruent] e \[LeftAngleBracket]\(\[Psi]\_n\%*\) | \(r\& \[Rule] \)\ | \[Psi]\ \_0\[RightAngleBracket]\)\)], "NumberedEquation", FontSize->16], Cell["is the dipole matrix element and ", "Text", FontSize->16], Cell[BoxData[ \(\[Omega]\_\(0 n\) = E\_0 - E\_n \[Congruent] \(E\_0 - E\_n\)\/\:f7d8\)], "NumberedEquation",\ FontSize->16], Cell[TextData[{ "is the frequency of the transition. It is instructive to compare ", Cell[BoxData[ \(W\_\(0 \[Rule] n\)\)]], " with the classical expression. In the classical approximation the energy \ rate radiated by a dipole ", Cell[BoxData[ \(\(d\& \[Rule] \)\)]], ", which oscillates with the frequency \[Omega] is" }], "Text", FontSize->16], Cell[BoxData[ \(P = \(4 \[Omega]\^4\)\/\(3 c\^3\) | \(d\& \[Rule] \)\( | \^2\)\)], \ "NumberedEquation", FontSize->16], Cell["\<\ It follows from here that the probability of radiation of one quantum is\ \>", "Text", FontSize->16], Cell[BoxData[ \(W = \(P\/\(\:f7d8\ \[Omega]\) = \(4 \[Omega]\^3\)\/\(3 \:f7d8\ c\^3\) \ | \(d\& \[Rule] \)\( | \^2\)\)\)], "NumberedEquation", FontSize->16], Cell["Compare this classical expression with the quantum one", "Text", FontSize->16], Cell[BoxData[ \(W\_\(0 \[Rule] n\) = \(4 \[Omega]\_\(0 n\)\%3\)\/\(3 \:f7d8\ c\^3\) \ | \(d\& \[Rule] \)\_\(n, 0\)\( | \^2\)\)], "NumberedEquation", FontSize->16], Cell["They match nicely.", "Text", FontSize->16] }, Open ]] }, Open ]] }, FrontEndVersion->"5.1 for Microsoft Windows", ScreenRectangle->{{0, 1024}, {0, 696}}, WindowToolbars->"RulerBar", WindowSize->{1016, 649}, WindowMargins->{{0, Automatic}, {Automatic, 0}}, PrintingCopies->1, PrintingPageRange->{Automatic, Automatic}, CellLabelAutoDelete->False, Magnification->1, StyleDefinitions -> "ArticleModern.nb" ] (******************************************************************* Cached data follows. 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